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.net ean 13 reader


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where the constant of integration A(no, n i ) does not depend on P, T. Accordingly we can find A(no, n i ) by making T so high and P so low that the solution completely evaporates and becomes a mixture of two ideal gases, the entropy of which we can explicitly calculate. It will be seen that the osmotic pressure arises solely from the term A(n o' n i ). The entropy of 1 mol of ideal gas at given T and P is seT, P) = cp log T - R log P + K (2.39) where K is a numerical constant. The entropy of a mixture of two ideal gases of no and n 1 moles respectively is Sidea1(T, P, no, n i )

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= (noc po + nicp,)logT- noR log Po - niRlogPi + noKo + niK i (2.40)

where Po and Pi are the partial pressures of the two gases. To express the entropy in terms of the total pressure P, we make use of the facts P = Po + Pi (2.41 )

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There are many terms used for these phenomenons A rounded top, as the name suggests, is price action at the upper end of a chart, and it is sometimes called a distribution top or an inverted saucer A saucer, which is typically at the low end of a chart s recent price range, is also referred to as a rounded bottom, a basing pattern, or a dish pattern Tops and bottoms are not always as clean and neat as saucers and tops, so we will begin by examining the more fundamental price breakouts, which are the progenitors of saucers and tops A breakout is the escape from a price range bounded by a lower line (support) and an upper line (resistance) Figure 91 illustrates a breakout pattern in which the price action had been around $7 to $9 for many months.

(2.42)

-niRlog(ni/n O)

(2.43)

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Comparison of this with (2.38) yields A(no, n i ) = - niR log (ni/n 0) + noKo + niKi (2.44) The first term on the right side is known as the entropy of mixing, which arises directly from the mixing of the two gases with additive partial pressures. It is the entropy of mixing that gives rise to osmotic pressure. The free energy of the solution can now be written in the form

A(T, P, no, n i ) = noao(T,

Click the Insert tab on the Ribbon and then the Quick Parts button. Click Save Selection to Quick Part Gallery. The Create New Building Block dialog box appears.

+ niRT log (ni/no)

(2.45) where a o is the free energy per mole of the pure solvent. The explicit forms of a i and a 0 are irrelevant to our purpose. To find the osmotic pressure, consider a solution separated from the pure solvent by a semipermeable membrane, as shown in Fig. 2.13. The pressure of the solution is by definition higher than that of the pure solvent by pI, the osmotic pressure. The total free energy of this composite system is

When prices broke above the resistance line in mid-June, the stock swiftly moved up several hundred percent 207.

+ no)ao + nia i + niRTlog(ni/n O)

(2.46)

Suppose the semipermeable membrane is displaced reversibly, with the tempera-

P+P'

(17.49)

where P, V, T respectively stand for pressure, volume, and temperature in units of the corresponding critical quantities. (Thus, for example, t = T - 1.) We shall take V as the order parameter and P as the conjugate field, and suppose that (17.49) is the result of minimizing a Landau free energy 1/1 (V, P, T), i.e., it is the equation a1/1/ aV = O. Thus, by integrating (17.49) at constant T and P, we obtain 3 8 1 1/1(V,P,T)=PV- V - 3"Tlog ( V- 3" )

(17.50)

Type a name for the entry or use the default name. You can also assign a gallery, a category and a description for the entry.

up to an undetermined function of T. (The P dependence is correct because P couples linearly to the order parameter V) A qualitative sketch of this function is shown in Fig. 17.2. Minimizing it with respect to V yields

breaking above its resistance level. Notice the pullback to the former resistance level after the breakout, after which the price soared.

~_T_

3 V-

~ = ~{~TIog(V _ ~) 2

(17.51)

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